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Lithium Thioarsenates

Lithium Orthothioarsenate, Li3AsS4.nH2O, is precipitated when alcohol is added to an aqueous solution of the pyro-salt; it forms colourless crystals which are soluble in water. If alcohol is added to the solution of the ortho-salt, lithium metathioarsenate, LiAsS3, is precipitated. Lithium pyrothioarsenate, Li4As2S7, separates as citron-yellow crystals when an aqueous solution of lithium monohydrogen orthoarsenate, saturated with hydrogen sulphide, is allowed to evaporate. The crystals are stable in the air.

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