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Thallium Orthothioarsenate, Tl3AsS4

Thallium Orthothioarsenate, Tl3AsS4, may be obtained by passing hydrogen sulphide into an alkaline solution containing an arsenate and a thallous salt. It forms an orange-coloured precipitate, decomposed by acids and on boiling with concentrated alkali sulphides. It is stable in air, but undergoes partial decomposition on heating.

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